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Handbook of Aggregation-Induced Emission, Volume 1
Читать книгу Handbook of Aggregation-Induced Emission, Volume 1 - Группа авторов - Страница 1
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Вернуться на страницу книги Handbook of Aggregation-Induced Emission, Volume 1
Оглавление
Страница 1
Table of Contents
List of Tables
List of Illustrations
Guide
Pages
Handbook of Aggregation‐Induced Emission Volume 1 Tutorial Lectures and Mechanism Studies
Страница 8
Страница 9
List of Contributors
Preface to Handbook of Aggregation‐Induced Emission
Preface to Volume 1: Fundamentals
1 The Mechanistic Understanding of the Importance of Molecular Motions to Aggregation‐induced Emission
1.1 Introduction
1.2 Restriction of Intramolecular Motion
1.2.1 Restriction of Intramolecular Rotation
1.2.2 Restriction of Intramolecular Vibration
1.2.3 Ultrafast Insights into Tetraphenylethylene Derivatives
1.2.4 Theoretical Insights into Restriction of Intramolecular Motion
1.3 Restricted Access to Conical Intersection
1.4 Restriction of Access to the Dark State
1.5 Suppression of Kasha’s Rule
1.6 Through Space Conjugation
1.6.1 Clusterization‐Triggered Emission
1.6.2 Polymerization‐induced Emission
1.6.3 Excited‐state Through‐space Conjugation
1.7 Perspective
References
2 Understanding the AIE Mechanism at the Molecular Level
2.1 Introduction
2.2 Theoretical Methods 2.2.1 Radiative and Nonradiative Rate Constants
2.2.2 Computational Details
2.3 Revealed AIE Mechanism
2.3.1 Rotating Vibrations of Intramolecular Aromatic Ring
2.3.2 Stretching Vibrations of Bonds
2.3.3 Bending Vibration of Bonds
2.3.4 Flipping Vibrations of Molecular Skeletons
2.3.5 Twisting Vibration of Molecular Skeletons
2.4 Visualize Calculated Parameters in Experiments
2.4.1 Stokes Shift vs Reorganization Energy
2.4.2 Resonance Raman Spectroscopy (RSS) vs Reorganization Energy
2.4.3 Isotope Effect vs DRE
2.4.4 Linear Relationship between Fluorescence Intensity and Amorphous Aggregate Size
2.4.5 Pressure‐induced Enhanced Emission (PIEE)
2.5 Molecular Design Based on AIE Mechanism
2.6 Summary and Outlook
Acknowledgments
References
3 Aggregation‐induced Emission from the Restriction of Double Bond Rotation at the Excited State
3.1 Introduction
3.2 AIE Phenomena and Applications from RDBR Mechanism 3.2.1 Evolvement and Development of AIE Mechanisms
3.2.2 Investigation of RDBR AIE Mechanism by
E
/
Z
isomerization
3.2.3 Investigating of RDBR AIE Mechanism by Immobilization of TPE Propeller‐like Conformation
3.2.4 Research of Theoretical Calculation on RDBR
3.2.5 Other AIEgens Involving RBDR Process
3.3 Conclusions
References
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