Читать книгу Supramolecular Polymers and Assemblies - Andreas Winter - Страница 2
Table of Contents
Оглавление1 Cover
4 Preface
7 1 Supramolecular Polymers: General Considerations* 1.1 Introduction 1.2 Classification Schemes 1.3 Supramolecular Polymerization Mechanisms 1.4 Beyond Classical Supramolecular Polymerization 1.5 Concluding Remarks References
8 2 Supramolecular Assemblies Based on Ionic Interactions 2.1 General Aspects 2.2 Basic Binding Modes and Discrete Model Assemblies 2.3 Supramolecular Polymers, Based on Ionic Interactions 2.4 Concluding Remarks References
9 3 Supramolecular Polymers, Based on Hydrogen‐Bonding Interactions* 3.1 General Aspects 3.2 From H‐Bonding Interactions to Supramolecular Polymers 3.3 Conclusion Remarks References
10 4 Supramolecular Polymers, Based on Metal‐to‐Ligand Interactions* 4.1 General Aspects 4.2 Synthesis and Design Principles 4.3 Linear Metallo‐supramolecular Polymers 4.4 Concluding Remarks References
11 5 Supramolecular Polymers, Based on π‐Electronic Interactions 5.1 General Aspects 5.2 Columnar Supramolecular Polymers, Based on π–π Stacking Interactions 5.3 From π–π Stacking to Advanced Donor–Acceptor‐Type Charge–Transfer Interactions 5.4 From Charge–Transfer to π‐Electronic Ion‐Pairing Interactions 5.5 Linear Supramolecular Polymers, Based on π‐Electronic Interactions 5.6 Conclusion and Outlook References
12 6 Supramolecular Polymers, Based on Crown Ether Recognition 6.1 General Aspects 6.2 From Crown Ether Molecular Recognition Toward Supramolecular Polymers 6.3 Mechanical Interlocking: From Pseudorotaxanes to Rotaxanes 6.4 Poly(pseudo)rotaxanes, Derived from Preformed Polymers 6.5 Supramolecular Amphiphiles 6.6 Concluding Remarks References
13 7 Supramolecular Polymers, Based on Cucurbiturils 7.1 General Aspects 7.2 Interactions of CB[n]s with Small Organic Guest Molecules 7.3 Supramolecular Polymers Incorporating CB[n] Units 7.4 Concluding Remarks References
14 8 Supramolecular Polymers, Based on the Host–Guest Chemistry of Calixarenes 8.1 General Aspects 8.2 Calixarene‐Based Supramolecular Polycaps 8.3 Supramolecular Polymers Featuring Vacant Calixarene Scaffolds 8.4 Supramolecular Polymers, Formed by Host–Guest Interactions 8.5 Beyond Classical Calix[n]arenes: Calix[4]pyrroles 8.6 Miscellaneous Supramacromolecular Assemblies, Based on Calixarenes 8.7 Concluding Remarks References
15 9 Cyclodextrins in the Field of Supramolecular Polymers 9.1 General Aspects 9.2 Cyclodextrins and Supramolecular Polymers 9.3 End‐Capping: From Polypseudorotaxanes to Polyrotaxanes 9.4 Polymerization of Pre‐assembled Pseudorotaxanes 9.5 Supramolecular Polymerization, Based on CD Recognition 9.6 Amphiphilic Supramolecular Diblock Copolymers 9.7 Concluding Remarks References
16 10 Supramolecular Polymers, Based on the Host–Guest Chemistry of Pillarenes 10.1 General Aspects 10.2 Host–Guest Complexation Between Pillarenes and Linear Polymers 10.3 Supramolecular Polymers, Derived from Pillarene‐based Host–Guest Interactions 10.4 Hyperbranched and Cross‐linked Assemblies 10.5 Supramolecular Assemblies, Based on Amphiphilic Pillar[5]arenes 10.6 Concluding Remarks References
17 11 Supramolecular Polymers, Formed by Orthogonal Non‐covalent Interactions* 11.1 Introduction 11.2 Orthogonal Combinations of Supramolecular Interactions Involving Metal‐to‐Ligand Coordination 11.3 Orthogonal Combinations of Supramolecular Interactions Involving H-Bonding 11.4 Miscellaneous Orthogonal Combinations of Supramolecular Interactions 11.5 Biomimetic Orthogonal Self‐Assembly: Protein Recognition 11.6 Concluding Remarks References
18 12 Characterization of Supramolecular Polymers 12.1 Introduction 12.2 Estimation of the Molar Mass from the Theories of Supramolecular Polymer Science 12.3 Size‐Exclusion Chromatography 12.4 Viscometry 12.5 Light Scattering 12.6 Vapor Pressure Osmometry 12.7 Analytical Ultracentrifugation 12.8 NMR Spectroscopy 12.9 Mass Spectrometry 12.10 Microscopy Imaging 12.11 Small/Wide‐Angle X‐Ray Scattering 12.12 X‐Ray Crystallography 12.13 Small‐Angle Neutron Scattering 12.14 Asymmetric Flow Field‐Flow Fractionation 12.15 Taylor Dispersion Analysis 12.16 They Are Very Complex Structures but Totally Timely … References
19 Index
