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Organofluorine Chemistry
Читать книгу Organofluorine Chemistry - Группа авторов - Страница 1
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Вернуться на страницу книги Organofluorine Chemistry
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Table of Contents
Pages
Organofluorine Chemistry Synthesis, Modeling, and Applications
Страница 5
Preface
1 The Development of New Reagents and Reactions for Synthetic Organofluorine Chemistry by Understanding the Unique Fluorine Effects
1.1 Introduction
1.2 The Unique Fluorine Effects in Organic Reactions
1.2.1 Fluorine‐Enabled Stability of “CuCF3” in Water, and the Unusual Water‐Promoted Trifluoromethylation
1.2.2 Fluorine Enables β‐Fluoride Elimination of Organocopper Species
1.2.3 The “Negative Fluorine Effect” Facilitates the α‐Elimination of Fluorocarbanions to Generate Difluorocarbene Species
1.2.4 Tackling the β‐Fluoride Elimination of Trifluoromethoxide Anion via a Fluoride Ion‐Mediated Process
1.3 The Relationships Among Fluoroalkylation, Fluoroolefination, and Fluorination
1.3.1 From Fluoroalkylation to Fluoroolefination
1.3.2 From Fluoroolefination to Fluoroalkylation
1.3.3 From Fluoroalkylation to Fluorination
1.4 Conclusions
References
2 Perfluoroalkylation Using Perfluorocarboxylic Acids and Anhydrides
2.1 Introduction
2.2 Perfluoroalkylation with Perfluorocarboxylic Acids
2.2.1 Electrochemical Reactions
2.2.1.1 Reactions of Alkenes and Alkynes
2.2.1.2 Reaction of Aromatic Compounds
2.2.2 Reactions Using XeF2
2.2.3 Reactions Using Copper and Silver Salts
2.2.3.1 Using Copper Salts
2.2.3.2 Using Silver Salts
2.2.4 Photochemical Reactions
2.2.5 Other Methods
2.2.5.1 Hydro‐Trifluoromethylation of Fullerene
2.2.5.2 Metal‐Free Aryldifluoromethylation Using S
2
O
8
2−
2.3 Perfluoroalkylation with Perfluorocarboxylic Anhydride
2.3.1 Reactions Using Perfluorocarboxylic Anhydride/Urea·H2O2
2.3.2 Photocatalytic Reactions Using Perfluorocarboxylic Anhydride/Pyridine N‐oxide
2.4 Summary and Prospects
References
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