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Electrolysis of perfluorocarboxylic acids and their metal salts can generate a perfluoroalkyl radical by anodic reaction, which was inspired by Kolbe electrosynthesis (Scheme 2.1) [3, 4]. The perfluoroalkyl radical can be electrophilically added to alkenes, alkynes, and aromatic compounds, and some examples are described below.

Scheme 2.1 Electrochemical generation of perfluoroalkyl radical.