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1.4.1 Recycling of Post‐Use Plastics

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Material recycling saves the energy expended for producing consumer plastic goods because it is the resin production (extraction, refining, and polymerization into resin) step, as opposed to the processing step, that has the higher embodied energy, EE (Schyns and Shaver 2020). Especially with single‐use products such as plastic cups, straws, or bags, the item is used only for a short duration and the quality of the plastic resin is barely affected by use. Being thermoplastic materials, the post‐use products can be collected and re‐melted for use in another generation of products. With most of the EE and embodied impacts associated with the manufacturing phase avoided, the strategy yields significant advantages (see Table 1.2). As seen from the table, savings in energy and in carbon emissions associated with recycling are substantial for plastics generally met with in the marine environment.

Even the leading type of plastic to be recycled in the US, PET bottles, are only recycled at a rate of ~28% presently. Even with bottles, the common use of the recyclate (r‐PET) resin is to “downcycle” into other products ( products of lower market value relative to the original high‐value bottle.) Alternatively, the r‐PET may be mixed with virgin PET (or used as a layer in multi‐layer extrusions) in fabricating original high‐value products. For instance, PET resin from plastic soda bottles might be downycled into textile or carpet fiber (Leonas 2017) and then downcycled again (mixed with other plastics) into lower value “plastic lumber” (Wan et al. 2019). Downcycling, however, is not the only recycling option available, as illustrated by the bottle‐to‐bottle recycling of PET, consistent with the paradigm of “circular economy.” To be sustainable, however, the US plastic industry also must join the ranks of high‐recyclers of the Word such as Norway, Sweden and South Korea, to recycle much higher fractions of at least the post‐consumer PET and HDPE, and encourage the recycling of other plastic resins as well.

Table 1.2 Comparison of the embodied energy (GJ/kg) and carbon footprint (kgCO2‐e) for virgin and recycled resin.

Based on data from Ashby (2013).

Plastic Embodied energy Virgin (GJ/kg) Embodied energy Recycled (GJ/kg) Carbon footprint Virgin (kgCO2‐e /kg) Carbon footprint Recycled (kgCO2‐e /kg)
Polyethylene 77–85 45–55 2.6–2.9 2.7–3.0
Polypropylene 75–83 45–55 2.9–3.2 2.0–2.2
Polyester (PET) 81–89 35–43 5.7–4.1 2.1–2.6
Polystyrene 92–102 43–52 3.6–4.0 2.6–3.1
Poly(vinyl chloride) 56–62 32–40 2.4–2.6 1.9–2.4
Nylon 6 116–129 38–47 7.6–8.3 2.3–2.8
Poly(lactic acid) 49–54 3.4–3.8 3.4–3.8 2.9–2.4

Low recycling rates in the US and elsewhere often result from the lack of readily‐accessible recycling infrastructure at the local level and the minimal market cost differential between virgin and recycled resin. Also, it is not always practical to mechanically recycle a mixed stream of plastic waste. For example, producing high‐quality recyclate is simply not possible with blends or multi‐layer laminated plastic products (Kaiser et al. 2018) or with products that are rendered photodegradable or enhanced biodegradable (a 0.5 wt% of biodegradable PLA contaminating a PET recycling stream discolors the rPET) (Alaerts et al. 2018). Some of waste plastics, however, may be amenable to recycling into chemical feedstock and energy via either pyrolysis or incineration. Recycling of waste fishing gear into plastic resin pellets, and their conversion to energy by incineration, are practiced at a small scale in the US, but much progress needs to be made.

Recycling does involve significant costs for collection, sorting, classifying, and cleaning of waste plastics, and there are incidental losses of material during the process that preclude a 100% mass recovery as the recyclate. Even with such losses, the savings in energy are substantial. There are, however, embedded impacts associated with the recycling process as well, and LCA must be carried out to make sure that most of what is saved in energy is not negated by increased environmental impacts. Also, each time a resin is recycled its mechanical characteristics detriorate; with PET, 3–5 repeated recycling results in ~50% decrease in tensile strength and extensibility of the resin (La Mantia and Vinci 1994).

Plastics and the Ocean

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