Читать книгу A History of Inventions, Discoveries, and Origins (Vol. 1&2) - Johann Beckmann - Страница 45

VERDIGRIS, or SPANISH GREEN.

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Respecting the preparation of verdigris, various and in part contradictory opinions have been entertained; and at present, when it is with certainty known, it appears that the process is almost the same as that employed in the time of Theophrastus, Dioscorides, and Vitruvius462. At that period, however, every natural green copper salt was comprehended under the name of ærugo. Dioscorides and Pliny say expressly, that a substance of the nature of those stones which yielded copper when melted, was scraped off in the mines of Cyprus; as is still practised in Hungary, where the outer coat of the copper ore is collected in the like manner, and afterwards purified by being washed in water. Another species, according to the account of Dioscorides, was procured from the water of a grotto in the same island; and the most saleable natural verdigris is still collected by a similar method in Hungary. The clear water which runs from old copper-works is put into large vessels, and after some time the green earth falls to the bottom as a sediment.

The artificial ærugo of the ancients, however, was our verdigris, or copper converted into a green salt by acetic acid. To discover the method of procuring this substance could not be difficult, as that metal contracts a green rust oftener than is wished, when in the least exposed to acids. The ancients, for this purpose, used either vessels and plates of copper, or only shavings and filings; and the acid they employed was either the sourest vinegar, or the sour remains left when they made wine; such as grapes become sour, or the stalks and skins after the juice had been pressed from them463. Sometimes the copper was only exposed to the vapour of vinegar in close vessels, so that it did not come into immediate contact with the acid; in the same manner as was practised with plates of lead in the time of Theophrastus, when white-lead was made, and as is still practised at present. Sometimes the metal was entirely covered with vinegar, or frequently besprinkled with it, and the green rust was from time to time scraped off; and sometimes copper filings were pounded with vinegar in a copper mortar, till they were changed into the wished-for green salt. This article was frequently adulterated, sometimes with stones, particularly pumice-stone reduced to powder, and sometimes with copperas. The first deception was easily discovered; and to detect the second, nothing was necessary but to roast the verdigris, which betrayed the iron by becoming red; or to add to the verdigris some gall-nut, the astringent ingredients of which united with the oxide of iron of the copperas, and formed a black ink.

In early periods verdigris was used principally for making plasters, and for other medicinal purposes; but it was employed also as a colour, and on that account it is by Vitruvius reckoned among the pigments. When applied to the former purpose, it appears that the copper salt was mixed with various other salts and ingredients. One mixture of this kind was called vermicular verdigris464, the accounts of which in ancient authors seem to some commentators to be obscure; but in my opinion we are to understand by them, that the ingredients were pounded together till the paste they formed assumed the appearance of pieces or threads like worms; and that from this resemblance they obtained their name. For the same reason the Italians give the name of vermicelli to wire-drawn paste of flour used in cookery465. When the process for making this kind of verdigris did not succeed, the workmen frequently added gum to it, by which the paste was rendered more viscous; but this mixture is censured both by Pliny and Dioscorides. It appears that the greater part of the verdigris in ancient times was made in Cyprus, which was celebrated for its copper-works, and in the island of Rhodes.

At present considerable quantities of verdigris are manufactured at Montpelier in France, and by processes more advantageous than those known to the ancients466. The dried stalks of grapes are steeped in strong wine, and with it brought to a sour fermentation. When the fermentation has ceased, they are put into an earthen pot, in alternate layers with plates of copper, the surface of which in a few days is corroded by the acetic acid, and the salt is then scraped off. It is certain, that, even in the fifteenth century, the making of verdigris was an old and profitable branch of commerce in France. The city of Montpelier having been obliged to expend large sums in erecting more extensive buildings to carry it on, and having had very small profits for some years before, received by letters patent from Charles VI., in 1411, permission to demand sixteen sous for every hundred weight of verdigris made there. In later times this trade has decayed very much. Between the years 1748 and 1755, from nine to ten thousand quintals were manufactured annually, by which the proprietors had a clear profit of 50,000 crowns; but a sudden change seems to have taken place, for in 1759 the quantity manufactured was estimated at only three thousand quintals. This quantity required 630 quintals of copper, valued at 78,750 livres: the expenses of labour amounted to 1323 livres; the necessary quantity of wine, 1033 measures, to 46,485 livres, and extraordinaries to 10,330 livres; so that the three thousand quintals cost the manufacturers about 136,888 livres. In the year 1759, the pound of verdigris sold for nine sous six deniers: so that the three thousand quintals produced 142,500 livres, which gave a net profit of only 5612 livres. Other nations, who till that period had purchased at least three-fourths of the French verdigris, made a variety of experiments in order to discover a method of corroding copper which might be cheaper; and some have so far succeeded that they can supply themselves without the French paint in cases of necessity467.

In commerce there is a kind of this substance known under the name of distilled verdigris, which is nothing else than verdigris purified, and crystallized by being again dissolved in vinegar468. For a considerable period this article was manufactured solely by the Dutch, and affords an additional example of the industry of that people. Formerly there was only one person at Grenoble acquainted with this art, which he kept secret and practised alone; but for some years past manufactories of the same kind have been established in various parts of Europe.

The German name of verdigris (Spangrün) has by most authors been translated Spanish green; and it has thence been concluded that we received that paint first from the Spaniards. This word and the explanation of it are both old; for we find ærugo, and viride Hispanicum, translated Spangrün, Spongrün, or Spansgrün, in many of the earliest dictionaries469, such as that printed in 1480470. For this meaning, however, I know no other proof than the above etymology, which carries with it very little probability; and I do not remember that I ever read in any other works that verdigris first came from the Spaniards.

FOOTNOTES

462 Dioscorid. lib. v. cap. 91, 92. Theophrastus De Lapidibus, edit. Heinsii, p. 399. Plin. lib. xxxiv. cap. 11, 12. Oribasius, lib. xiii. Stephani Medicæ Artis Principes, p. 453. Vitruv. lib. vii. cap. 12.

463 Plinius: vinacea. Dioscorides: στέμφυλα. Theophrastus: τρύξ. The last word has various meanings: sometimes it signifies squeezed grapes; sometimes wine lees, &c., of which Niclas gives examples in his Observations on Geop. lib. vi. c. 13, p. 457; but it can never be translated by amurca, though that word is used by Furlanus, the translator of Theophrastus. The old glossary says, Ἀμοργὴ, ἐστὶν δὲ τρὺξ ἐλαιου. Oil, however, has nothing to do with verdigris.

464 Ἰὸς σκώληξ, ærugo scolacea, or vermicularis.

465 Should this explanation be just, we ought for æruca, the name given by Vitruvius to verdigris, to read eruca: though the conjecture of Marcellus Vergilius (Dioscorides, interprete Mar. Vergilio. Coloniæ, 1529, fol. p. 656), that the reading should be ænea or ærea, is no less probable; for by this epithet its difference from ærugo ferri was frequently distinguished.

466 [Dr. Ure states, in his Dictionary of Arts and Manufactures, that the manufacture of verdigris at Montpelier is altogether domestic. In most wine farm-houses there is a verdigris cellar; and its principal operations are conducted by the females of the family. They consider the forming the strata, and scraping off the verdigris the most troublesome part.]

467 [In England large quantities of verdigris are now prepared by arranging plates of copper alternately with pieces of coarse woollen cloth steeped in crude pyroligneous acid, which is obtained by the destructive distillation of wood.]

468 [Verdigris is a mixture of three compounds of acetic acid with oxide of copper, which contain a preponderance of the base, hence basic acetates; distilled verdigris is made by digesting verdigris, or the mixture of basic acetates of copper, with excess of acetic acid and crystallizing by evaporation: the acid then exists in such proportions as to form a neutral acetate of copper.]

469 Frisch’s Worterbuch, p. 291. In the works of George Agricola, printed together at Basle, 1546, fol., we find in p. 473, where the terms of art are explained, “Ærugo, Grünspan, or Spansch-grün, quod primo ab Hispanis ad Germanos sit allata; barbari nominant viride æris.”

470 By Conrad Zeninger, Nuremberg. In that scarce work, Josua Maaler, Teutsche Spraach oder Dictionarium Germano-Latinum, Zurich, 1561, 4to, ærugo is called Spangrüne.