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Dry-cells and Batteries

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Dry-cells are extensively used nowadays, since their cleanliness, high efficiency, and low internal resistance make them preferable to the Leclanché and other open-circuit batteries for bells, annunciators, and other light work. In the dry-cell, the electrolyte, instead of being a liquid, is a gelatinous or semi-solid mass, which will not run nor slop over. When the capping of pitch or tar is in place, the cell may be placed in any position, with full assurance that the electrolyte will not become displaced nor run out. Dry-cells may be made of almost any size for convenience of handling, but those commonly used vary from one to four inches in diameter, and from four to fifteen inches high. For bells and general electric work, a cell two inches and a half in diameter and seven inches high will be found a convenient size to make and handle.

The component parts of a dry-cell are the cell itself (which is made of zinc and acts as the positive pole), the carbon, the electrolyte or active excitant element, and the pitch or tar cap to hold the electrolyte and carbon in place.

From a tinsmith obtain some pieces of sheet zinc, and roll them into cylindrical form as shown in Fig. 18 A. The sheets should measure seven by eight inches, and when formed the edges are to be lapped and soldered.

From a smaller piece of zinc cut round bottoms, fit them in the cylinders and solder securely in place, taking care to close up all seams or joints to prevent the escape of the electrolyte.

From a supply-house obtain battery-carbons, one inch and a half wide by half or three-eighths of an inch thick and eight inches long. These should be provided with a thumb-screw or small bolt and nut at the top so as to make wire connections with the carbon. A strip of zinc should be soldered to the outside upper edge of the zinc cup to which wire attachments may be made with thumb-screws or small bolts and nuts. When the parts are ready to assemble, make a wooden mould or form a trifle larger than the carbon. This is intended to act as a temporary plunger, and is inserted, at first, in place of the carbon plate. This wooden plunger should be smooth, and given a coat of shellac to prevent it from absorbing any moisture.

Insert the plunger in the zinc cup and support it so that it will be at least half an inch above the bottom and centred at the middle of the cup. The electrolyte is then placed in the cup, and, when it has set a little, the wooden plunger is removed and the carbon inserted in its place.

The electrolyte is composed as follows:

Ammonium chloride 1 part
Zinc chloride 1 part
Plaster of Paris 3 parts
Flour ¾ part
Water 2 parts

Mix these together and place the compound within the zinc cups, so that the mass settles down and packs closely about the plunger. The space left unfilled about the carbon should be filled with a mixture composed as follows:

Ammonium chloride 1 part
Zinc chloride 1 part
Manganese binoxide 1 part
Granulated carbon 1 part
Flour 1 part
Plaster of Paris 3 parts
Water 2 parts

These proportions may be measured in a tin cup, a table-spoon, or any other small receptacle. Note that the measurement by parts is always by bulk and not by weight.

Do not fill the zinc cup to the top, but leave an inch of space, so that half an inch of sealing material may be added. See that the inside top edge of the zinc cup is clean; then melt some tar or pitch and pour it over the top of the electrolyte, so that it binds the zinc cup and carbon into a solid form. Drive an awl down through the capping material when it is nearly dry, and leave the holes open for the escapement of gases.

Give the outer surface of the zinc cells a coat of asphaltum varnish, and wrap several thicknesses of heavy paper about them to prevent contact and short-circuiting. Protect the bottoms in a similar manner, and as a result you will have a cell that will appear as shown in Fig. 18 B. A battery of cells powerful enough for any light work can be made by connecting the cells in series, each having an electro-motive force of one and a half volts, with an internal resistance of less than one-third of an ohm.

Harper's Electricity Book for Boys

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