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1.2.1 Acids

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Acids serve a variety of functions in foods including flavor enhancement, control of microbial growth, protein coagulation, emulsification, control of browning, buffering action, and metal chelation (to control lipid oxidation). All acids have a sour taste but different acids produce distinctively different sour flavors. Thus, it is not enough to simply add any acid when attempting to produce a characteristic sour flavor in a food. Table 1.1 gives structures and pK values of some common food acids.

Table 1.1 Acids common in foods: structures and pKa values.

Substance Structure pKa Food found in
Acetic acid pK = 4.75 Vinegar, figs
Adipic acid pK1 = 4.43 pK2 = 5.62 Beets
Butyric acid pK = 4.82 Cheese, butter
Citric acid pK1 = 3.06 pK2 = 4.74 pK3 = 5.40 Oranges, lemons, apricots, tomatoes
Lactic acid pK = 3.83 Yogurt, buttermilk, cheese, beer
Malic acid pK1 = 3.40 pK2 = 5.05 Apples, apricots, grapes, oranges, tomatoes
Oxalic acid pK1 = 1.27 pK2 = 4.27 Spinach, potatoes, tomatoes
Phosphoric acid pK1 = 2.12 pK2 = 7.21 pK3 = 12.32 Tomatoes, acidulant used in soft drinks
Tartaric acid pK1 = 2.98 pK2 = 4.34 Grapes
Sodium hydrogen sulfate or sodium acid sulfate pK = 1.99 Acidulant. Lowers pH without imparting acid taste. May be added to process water to enhance chlorine activity
Food Chemistry

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