Читать книгу Methodologies in Amine Synthesis - Группа авторов - Страница 37

As introduced in Section 3.2, construction of C—N bonds via N‐radical addition pathway relies on N‐centered radical (or radical cation) species, generated by oxidation of N—H bonds, as key intermediates. On the contrary, aminations via N‐atom nucleophilic addition pathway proceed through the oxidation of the C–H partners, and the amines usually serve as nucleophiles to attack the generated C‐centered cationic intermediates during the C—N bonds forming processes.