Читать книгу Methodologies in Amine Synthesis - Группа авторов - Страница 40

In the early years, C(sp³)–H amination reactions were mainly achieved via transition metal catalysis or with hypervalent iodine reagents. Recently, quite a few methods for CDC amination of activated C(sp³)—H bonds, such as benzylic C(sp³)–H and C(sp³)–H in α-position to a nitrogen atom, have been realized via the formation of the corresponding cationic species and subsequent addition of nitrogen nucleophiles by means of photo/electrochemistry.