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1.3 Application and Market Studies of CO2 Hydrogenation Products

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Hydrogenation of CO2 could be an efficient option for developing more environment‐friendly products as alternatives to fossil‐based ones. In terms of practicality, the distribution infrastructure of carbon‐based chemicals is well established. However, their manufacturing is currently several times more expensive than their conventionally produced counterparts, mainly due to the costs associated with H2 production. Some of the key features of CO2 hydrogenation products and conventional fuels are given in Table 1.2.

Table 1.2 Characteristics of various energy vectors.

Compound Energy density (GJ m−3) Approx. price per energy (US$/GJ) Boiling point/melting point (°C) Ignition point/flash point (°C) Vapor pressure at 25 °C (kPa)
Methanol 15.8 15 64.55/–97.68 470/15 (open) 16.9
Formic acid 6.3 100 100.56/8.27 520/59 (open) 43.1
Natural gas (CH4) 8.1 (20 MPa) 2 –161/–183 537/–188 147 (15 °C)
Gasoline 34.5 30 17–220/≤–40 300/≤–43 50–93 (37.8 °C)
Diesel oil 36.3 23 140–400/–29 to –18 250/40–70 ≤0.35 (37.8 °C)
Hydrogen 5.1 (70 MPa) 120 –252.87/–259.14 500–571/— 1.65 × 105
CO2 Hydrogenation Catalysis

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