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2.6.3 Crystallization of Perovskite
Оглавление1 i. Pumping through vacuumVacuum flash assisted arrangement process (VASP) was developed to enable the rapid expulsion of dissolution into a supersaturation eruption to quickly crystallise the FA0.81MA0.15PbI2.51Br0.45 perovskite [83]. The substrate can be first turn covered with perovskite antecedent arrangement and afterward moved to a vacuum hall to permit fast dissipation of the dissolvable. The film tempered at 100 °C to finish gem development.
2 ii. Formation of perovskite in two stepsFor the two-advance technique, initially save the PbX2 surface, trailed with the transformation to perovskite in natural arrangement of cation/halide [48, 84-85]. Since the testimony forms and the control system of PbX2 layers are more adaptable, the standard and complete incorporation may possibly be obtained, which will usually enhance the quality of the perovskite film [86]. reported novel work on the two schemes for PSCs which has observed PCE of around 15%. Long after, a huge exertion has been directed on this strategy, because of its high operability and great execution reproducibility. Above all, the incredible advancement on the response/development system brought about adjusted two-advance procedures, which very much improved perovskite quality and upgraded gadget execution. Similarly, two development instruments of the MAPbI3-perovskite are also presented: (i) interfacial response of direct solid-liquid at low methyl ammonium iodide (MAI) and (ii) dissolution crystallization at high MAI fixation [84, 87]. Many researchers addressed two development instruments in two-enhance statement technique [88,89]. When the MAI focus is under 8 mg/mL, an in situ change (interfacial response) continues inside 120 sec. If MA focus is more than 10 mg/mL in quantity, MAPbI3 perovskite gems structure promptly through a solid-liquid inter-facial response. Further response of MAI for hidden PbI2 is stifled, driving the inadequate response.