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2.3.4.2.1 Advanced Oxidation Processes

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Highly reactive free radicals such as HO•, HO2•, and O2•, generated from hydrogen peroxide or ozone in combination with a catalyst or UV or γ radiation, can be used to degrade pharmaceuticals in water (Wang et al., 2019). Advanced oxidation processes use oxidants such as O3 separately, O3 integrated with O3/H2O2, UV/H2O2, Fe2+/H2O2, and Fenton degradation. The photon-initiated carbon-halogen bond breakage and superior HO• generation make these processes more effective than O3 on its own (Patel et al., 2019). Consequently, high removals of a range of pharmaceutical compounds from aqueous solution have been achieved. In addition, UV or visible radiation can produce reactive excited states of the pharmaceutical compounds. The major limitation of advanced oxidation processes, however, is the formation of toxic byproducts which can persist in the treated water (Patel et al., 2019).

Applied Water Science

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