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a) Definition of the shear rate using differential variables

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Equation 2.3

γ ̇ = dv/dh

flowing layers, and the “infinitely” (differentially) small thickness dh of a single flowing layer (see Figure 2.2).

Table 2.1: Typical shear rates of technical processes
ProcessShear rates γ ̇ (s-1)Practical examples
physical aging, long-term creep within days and up to several years10-8 ... 10-5solid polymers, asphalt
cold flow10-8 ... 0.01rubber mixtures, elastomers
sedimentation of particles≤ 0.001 ... 0.01emulsion paints, ceramic suspensions, fruit juices
surface leveling of coatings0.01 ... 0.1coatings, paints, printing inks
sagging of coatings, dripping, flow under gravity0.01 ... 1emulsion paints, plasters, chocolate melt (couverture)
self-leveling at low-shear conditions in the range of the zero-shear viscosity≤ 0.1silicones (PDMS)
mouth sensation1 ... 10food
dip coating1 ... 100dip coatings, candy masses
applicator roller, at the coating head1 ... 100paper coatings
thermoforming1 ... 100polymers
mixing, kneading1 ... 100rubbers, elastomers
chewing, swallowing10 ... 100jelly babies, yogurt, cheese
spreading10 ... 1000butter, spreadcheese
extrusion10 ... 1000polymer melts, dough,ceramic pastes, tooth paste
pipe flow, capillary flow10 ... 104crude oils, paints, juices, blood
mixing, stirring10 ... 104emulsions, plastisols,polymer blends
injection molding100 ... 104polymer melts, ceramic suspensions
coating, painting, brushing, rolling, blade coating (manually)100 ... 104brush coatings, emulsion paints, wall paper paste, plasters
spraying1000 ... 104spray coatings, fuels, nose spray aerosols, adhesives
impact-like loading1000 ... 105solid polymers
milling pigments in fluid bases1000 ... 105pigment pastes for paints and printing inks
rubbing1000 ... 105skin creams, lotions, ointments
spinning process1000 ... 105polymer melts, polymer fibers
blade coating (by machine), high-speed coating1000 ... 107paper coatings, adhesive dispersions
lubrication of engine parts1000 ... 107mineral oils, lubricating greases

There is a linear velocity distribution between the plates, since the velocity v decreases linearly in the shear gap. Thus, for laminar and ideal-viscous flow, the velocity difference between all neighboring layers are showing the same value: dv = const. All the layers are assumed to have the same thickness: dh = const. Therefore, the shear rate is showing a constant value everywhere between the plates of the Two-Plates model since

γ ̇ = dv/dh = const/const = const (see Figure 2.3).


Figure 2.3: Velocity distribution and shear rate in the shear gap of the Two-Plates model

Both γ ̇ and v provide information about the velocity of a flowing fluid. The advantage of selecting the shear rate is that it shows a constant value throughout the whole shear gap. Therefore, the shear rate is independent of the position of any flowing layer in the shear gap. Of course, this applies only if the shear conditions are met as mentioned in the beginning of Chapter 2.2. However, this does not apply to the velocity v which decreases from the maximum value vmax on the upper, movable plate to the minimum value vmin = 0 on the lower, immovable plate. Therefore, when testing pure liquids, sometimes as a synonym for shear rate the term velocity gradient is used (e. g. in ASTM D4092).

The Rheology Handbook

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