Читать книгу Catalytic Asymmetric Synthesis - Группа авторов - Страница 30

Hong reported the synthesis of a steroid skeleton by a one‐pot reaction starting from an α,β‐unsaturated aldehyde and a nitroalkane (Eq. 1.30). A domino Michael/Michael reaction proceeded, followed by aldol and Henry reaction in a one‐pot operation, to afford a steroid skeleton with excellent enantioselectivity [58].

(1.30)