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§ 11. Mechanical Equivalent of Heat deduced from Velocity of Sound

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The question, then, of the correctness of this ratio involves the other and apparently incongruous question, whether atmospheric air possesses any sensible radiative power. If the ratio be correct, the practical absence of radiative power on the part of air is demonstrated. How then are we to ascertain whether the ratio is correct or not? By a process of reasoning which illustrates still further how natural agencies are intertwined. It was this ratio, looked at by a man of genius, named Mayer, which helped him to a clearer and a grander conception of the relation and interaction of the forces of inorganic and organic nature than any philosopher up to his time had attained. Mayer was the first to see that the excess 0·42 of the specific heat at constant pressure over that at constant volume was the quantity of heat consumed in the work performed by the expanding gas. Assuming the air to be confined laterally and to expand in a vertical direction, in which direction it would simply have to lift the weight of the atmosphere, he attempted to calculate the precise amount of heat consumed in the raising of this or any other weight. He thus sought to determine the “mechanical equivalent” of heat. In the combination of his data his mind was clear, but for the numerical correctness of these data he was obliged to rely upon the experimenters of his age. Their results, though approximately correct, were not so correct as the transcendent experimental ability of Regnault, aided by the last refinements of constructive skill, afterward made them. Without changing in the slightest degree the method of his thought or the structure of his calculation, the simple introduction of the exact numerical data into the formula of Mayer brings out the true mechanical equivalent of heat.

But how are we able to speak thus confidently of the accuracy of this equivalent? We are enabled to do so by the labors of an Englishman, who worked at this subject contemporaneously with Mayer; and who, while animated by the creative genius of his celebrated German brother, enjoyed also the opportunity of bringing the inspirations of that genius to the test of experiment. By the immortal experiments of Mr. Joule, the mutual convertibility of mechanical work and heat was first conclusively established. And “Joule’s equivalent,” as it is rightly called, considering the amount of resolute labor and skill expended in its determination, is almost identical with that derived from the formula of Mayer.

Sound

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