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Consider now the ground we have trodden, the curious labyrinth of reasoning and experiment through which we have passed. We started with the observed and calculated velocities of sound in atmospheric air. We found Laplace, by a special assumption, deducing from these velocities the ratio of the specific heat of air at constant pressure to its specific heat at constant volume. We found Mayer calculating from this ratio the mechanical equivalent of heat; finally, we found Joule determining the same equivalent by direct experiments on the friction of solids and liquids. And what is the result? Mr. Joule’s experiments prove the result of Mayer to be the true one; they therefore prove the ratio determined by Laplace to be the true ratio; and, because they do this, they prove at the same time the practical absence of radiative power in atmospheric air. It seems a long step from the stirring of water, or the rubbing together of iron plates in Joule’s experiments, to the radiation of the atoms of our atmosphere; both questions are, however, connected by the line of reasoning here followed out.

But the true physical philosopher never rests content with an inference when an experiment to verify or contravene it is possible. The foregoing argument is clinched by bringing the radiative power of atmospheric air to a direct test. When this is done, experiment and reasoning are found to agree; air being proved to be a body sensibly devoid of radiative and absorptive power.23

But here the experimenter on the transmission of sound through gases needs a word of warning. In Laplace’s day, and long subsequently, it was thought that gases of all kinds possessed only an infinitesimal power of radiation; but that this is not the case is now well established. It would be rash to assume that, in the case of such bodies as ammonia, aqueous vapor, sulphurous acid, and olefiant gas, their enormous radiative powers do not interfere with the application of the formula of Laplace. It behooves us to inquire whether the ratio of the two specific heats deduced from the velocity of sound in these bodies is the true ratio; and whether, if the true ratio could be found by other methods, its square root, multiplied into the calculated velocity, would give the observed velocity. From the moment heat first appears in the condensation and cold in the rarefaction of a sonorous wave in any of those gases, the radiative power comes into play to abolish the difference of temperature. The condensed part of the wave is on this account rendered more flaccid and the rarefied part less flaccid than it would otherwise be, and with a sufficiently high radiative power the velocity of sound, instead of coinciding with that derived from the formula of Laplace, must approximate to that derived from the more simple formula of Newton.