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§ 13. Velocity of Sound through Gases, Liquids, and Solids

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To complete our knowledge of the transmission of sound through gases, a table is here added from the excellent researches of Dulong, who employed in his experiments a method which shall be subsequently explained:

Velocity of Sound in Gases at the Temperature of 0° C.

Velocity
Air 1,092 feet
Oxygen 1,040
Hydrogen 4,164
Carbonic acid 858
Carbonic oxide 1,107
Protoxide of nitrogen 859
Olefiant gas 1,030

According to theory, the velocities of sound in oxygen and hydrogen are inversely proportional to the square roots of the densities of the two gases. We here find this theoretic deduction verified by experiment. Oxygen being sixteen times heavier than hydrogen, the velocity of sound in the latter gas ought, according to the above law, to be four times its velocity in the former; hence, the velocity in oxygen being 1,040, in hydrogen calculation would make it 4,160. Experiment, we see, makes it 4,164.

The velocity of sound in liquids may be determined theoretically, as Newton determined its velocity in air; for the density of a liquid is easily determined, and its elasticity can be measured by subjecting it to compression. In the case of water, the calculated and the observed velocities agree so closely as to prove that the changes of temperature produced by a sound-wave in water have no sensible influence upon the velocity. In a series of memorable experiments in the Lake of Geneva, MM. Colladon and Sturm determined the velocity of sound through water, and made it 4,708 feet a second. By a mode of experiment which you will subsequently be able to comprehend, the late M. Wertheim determined the velocity through various liquids, and in the following table I have collected his results:

Transmission of Sound through Liquids

Name of Liquid Temperature Velocity
River-water (Seine) 15° C. 4,714 feet
River”water (S” 30 5,013
River”water (S” 60 5,657
Sea-water (artificial) 20 4,768
Solution of common salt 18 5,132
Solution of sulphate of soda 20 5,194
Solution of carbonate of soda 22 5,230
Solution of nitrate of soda 21 5,477
Solution of chloride of calcium 23 6,493
Common alcohol 20 4,218
Absolute alcohol 23 3,804
Spirits of turpentine 24 3,976
Sulphuric ether 0 3,801

We learn from this table that sound travels with different velocities through different liquids; that a salt dissolved in water augments the velocity, and that the salt which produces the greatest augmentation is chloride of calcium. The experiments also teach us that in water, as in air, the velocity augments with the temperature. At a temperature of 15° C., for example, the velocity in Seine water is 4,714 feet, at 30° it is 5,013 feet, and at 60° 5,657 feet a second.

I have said that from the compressibility of a liquid, determined by proper measurements, the velocity of sound through the liquid may be deduced. Conversely, from the velocity of sound in a liquid, the compressibility of the liquid may be deduced. Wertheim compared a series of compressibilities deduced from his experiments on sound with a similar series obtained directly by M. Grassi. The agreement of both, exhibited in the following table, is a strong confirmation of the accuracy of the method pursued by Wertheim:

Cubic compressibility
╭———————^———————╮
from Wertheim’s velocity of sound from the direct experiments of M. Grassi
Sea-water 0·0000467 0·0000436
Solution of common salt 0·0000349 0·0000321
” carbonate of soda 0·0000337 0·0000297
” nitrate of soda 0·0000301 0·0000295
Absolute alcohol 0·0000947 0·0000991
Sulphuric ether 0·0001002 0·0001110

The greater the resistance which a liquid offers to compression, the more promptly and forcibly will it return to its original volume after it has been compressed. The less the compressibility, therefore, the greater is the elasticity, and consequently, other things being equal, the greater the velocity of sound through the liquid.

We have now to examine the transmission of sound through solids. Here, as a general rule, the elasticity, as compared with the density, is greater than in liquids, and consequently the propagation of sound is more rapid.

In the following table the velocity of sound through various metals, as determined by Wertheim, is recorded:

Velocity of Sound through Metals

Name of Metal At 20° C. At 100° C. At 200° C.
Lead 4,030 3,951 … …
Gold 5,717 5,640 5,619
Silver 8,553 8,658 8,127
Copper 11,666 10,802 9,690
Platinum 8,815 8,437 8,079
Iron 16,822 17,386 15,483
Iron wire (ordinary) 16,130 16,728 … …
Cast steel 16,357 16,153 15,709
Steel wire (English) 15,470 17,201 16,394
Steel wire 16,023 16,443 … …

As a general rule, the velocity of sound through metals is diminished by augmented temperature; iron is, however, a striking exception to this rule, but it is only within certain limits an exception. While, for example, a rise of temperature from 20° to 100° C. in the case of copper causes the velocity to fall from 11,666 to 10,802, the same rise produces in the case of iron an increase of velocity from 16,822 to 17,386. Between 100° and 200°, however, we see that iron falls from the last figure to 15,483. In iron, therefore, up to a certain point, the elasticity is augmented by heat; beyond that point it is lowered. Silver is also an example of the same kind.

The difference of velocity in iron and in air may be illustrated by the following instructive experiment: Choose one of the longest horizontal bars employed for fencing in Hyde Park; and let an assistant strike the bar at one end while the ear of the observer is held close to the bar at a considerable distance from the point struck. Two sounds will reach the ear in succession; the first being transmitted through the iron and the second through the air. This effect was obtained by M. Biot, in his experiments on the iron water-pipes of Paris.

The transmission of sound through a solid depends on the manner in which the molecules of the solid are arranged. If the body be homogeneous and without structure, sound is transmitted through it equally well in all directions. But this is not the case when the body, whether inorganic like a crystal or organic like a tree, possesses a definite structure. This is also true of other things than sound. Subjecting, for example, a sphere of wood to the action of a magnet, it is not equally affected in all directions. It is repelled by the pole of the magnet, but it is most strongly repelled when the force acts along the fibre. Heat also is conducted with different facilities in different directions through wood. It is most freely conducted along the fibre, and it passes more freely across the ligneous layers than along them. Wood, therefore, possesses three unequal axes of calorific conduction. These, established by myself, coincide with the axes of elasticity discovered by Savart. MM. Wertheim and Chevandier have determined the velocity of sound along these three axes and obtained the following results:

Velocity of Sound in Wood

Name of Wood Along Fibre Across Rings Along Rings
Acacia 15,467 4,840 4,436
Fir 15,218 4,382 2,572
Beech 10,965 6,028 4,643
Oak 12,622 5,036 4,229
Pine 10,900 4,611 2,605
Elm 13,516 4,665 3,324
Sycamore 14,639 4,916 3,728
Ash 15,314 4,567 4,142
Alder 15,306 4,491 3,423
Aspen 16,677 5,297 2,987
Maple 13,472 5,047 3,401
Poplar 14,050 4,600 3,444

Separating a cube from the bark-wood of a good-sized tree, where the rings for a short distance may be regarded as straight: then, if A R, Fig. 14, be the section Fig. 14. of the tree, the velocity of the sound in the direction m n, through such a cube, is greater than in the direction a b.

The foregoing table strikingly illustrates the influence of molecular structure. The great majority of crystals show differences of the same kind. Such bodies, for the most part, have their molecules arranged in different degrees of proximity in different directions, and where this occurs there are sure to be differences in the transmission and manifestation of heat, light, electricity, magnetism, and sound.

Sound

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