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2.3.6 Heavy Metal Contamination and Health Risk Index

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The health risk assessment is directly associated with the level of human exposure of the various contaminants, especially heavy metals through different mediums including air, water, and food items. In this study, the heavy metals were also estimated in the aquatic species and most frequently cultivated vegetation species, i.e. sorghum, wheat, grains, and rice, and compared with the standard permissible limits and the previously reported values for the same crops (Table 2.5). Further, the HRI due to heavy metal contamination was calculated as per the standard formula (Khan et al. 2010; Singh et al. 2018) and the guidelines of the United States Environmental Protection Agency (USEPA 2006) for the cultivated crop grains of wheat, maize, and rice to understand the potential human health issues of the dependent population (Figure 2.10).

Table 2.4 Sediment quality parameters of the Kanwar wetland.

Parameters Current study
Physical parameters
WHC (%) 49.6–65.5
Bulk density (g/cc) 0.77–0.86
pH 6.5–8.76
Electrical conductivity (μS/Cm) 115–136
Macronutrients
Organic carbon (%) 0.14–2.7
Available N (mg/kg) 1110–5831
Available P (mg/kg) 79.1–665
Available K (mg/kg) 89–1017
Available S (mg/kg) 82.2–226.5
Micronutrients, i.e. heavy metals Sediment quality guidelines
GRSa GDSb UCCc Ontario MoEd USEPA
Cr (mg/kg) 34–234 150 97 83 26–110 25–75
Mn (mg/kg) 217–1108 1715 1075 600 460–1100 NA
Cu (mg/kg) 14.6–118 55 25 25 16–110 25–50
Zn (mg/kg) 119–608 106 76 71 120–820 90–200
Pb (mg/kg) 15.6–223 23 NA 17 31–250 NA
Cd (mg/kg) 0–1.6 0.55 NA 0.098 0.6–10 NA

GRS: Ganga river sediments; GDS: Ganga delta sediment; UCC: upper continental crust; MoE: Ministry of Environment; USEPA: United States Environmental Protection Agency.

a Singh et al. (2003).

b Datta and Subramanian (1998).

c McLennan (2001).

d McDonald et al. (2000).

Table 2.5 Heavy metal content in various species of the Kanwar wetland.

Species Cr (mg/kg) Mn (mg/kg) Cu (mg/kg) Zn (mg/kg) Pb (mg/kg) Cd (mg/kg)
Hydrilla 111–164 116–148 38.5–55 9.6–12.85 133–158 0.89–0.98
Eichhornia 172–224 72–88 48–72 8.0–18 212–252 1.8–2.8
Lotus 28–46 26–42 12–31 6.0–22 114–163 1.02–1.8
Fish 22–36 12.0–26 5.3–21.5 6.24–20 146–172 0.97–1
Sorghum 58–92 12.6–23 22.5–52 4.0–15 217–264 1.01–1.26
Wheat 38.3–42 24–25.7 27.2–39 8.52–9.63 95.9–101 0.98–1.25
Maize 32–34.41 16.5–19 15.2–16.9 7.15–8.27 89–111 0.97–1.1
Rice 42–46.63 8.14–8.93 23–25.44 5.5–6.2 101–105 0.9–1.15
Permissible limit 1a 1b 30b 50b 5c 0.3c
Indian Standardd 20 NA 30 50 2.5 1.5

NA: not available.

a GB2762 (2012).

b CODEX (2001).

c FAO/WHO (2011).

d Awashthi (2000).


Figure 2.10 Health risk index of heavy metals via cultivated crop grains in the Kanwar wetland.

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