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2.3.6 Heavy Metal Contamination and Health Risk Index
ОглавлениеThe health risk assessment is directly associated with the level of human exposure of the various contaminants, especially heavy metals through different mediums including air, water, and food items. In this study, the heavy metals were also estimated in the aquatic species and most frequently cultivated vegetation species, i.e. sorghum, wheat, grains, and rice, and compared with the standard permissible limits and the previously reported values for the same crops (Table 2.5). Further, the HRI due to heavy metal contamination was calculated as per the standard formula (Khan et al. 2010; Singh et al. 2018) and the guidelines of the United States Environmental Protection Agency (USEPA 2006) for the cultivated crop grains of wheat, maize, and rice to understand the potential human health issues of the dependent population (Figure 2.10).
Table 2.4 Sediment quality parameters of the Kanwar wetland.
Parameters | Current study | |||||
---|---|---|---|---|---|---|
Physical parameters | ||||||
WHC (%) | 49.6–65.5 | |||||
Bulk density (g/cc) | 0.77–0.86 | |||||
pH | 6.5–8.76 | |||||
Electrical conductivity (μS/Cm) | 115–136 | |||||
Macronutrients | ||||||
Organic carbon (%) | 0.14–2.7 | |||||
Available N (mg/kg) | 1110–5831 | |||||
Available P (mg/kg) | 79.1–665 | |||||
Available K (mg/kg) | 89–1017 | |||||
Available S (mg/kg) | 82.2–226.5 | |||||
Micronutrients, i.e. heavy metals | Sediment quality guidelines | |||||
GRSa | GDSb | UCCc | Ontario MoEd | USEPA | ||
Cr (mg/kg) | 34–234 | 150 | 97 | 83 | 26–110 | 25–75 |
Mn (mg/kg) | 217–1108 | 1715 | 1075 | 600 | 460–1100 | NA |
Cu (mg/kg) | 14.6–118 | 55 | 25 | 25 | 16–110 | 25–50 |
Zn (mg/kg) | 119–608 | 106 | 76 | 71 | 120–820 | 90–200 |
Pb (mg/kg) | 15.6–223 | 23 | NA | 17 | 31–250 | NA |
Cd (mg/kg) | 0–1.6 | 0.55 | NA | 0.098 | 0.6–10 | NA |
GRS: Ganga river sediments; GDS: Ganga delta sediment; UCC: upper continental crust; MoE: Ministry of Environment; USEPA: United States Environmental Protection Agency.
a Singh et al. (2003).
b Datta and Subramanian (1998).
c McLennan (2001).
d McDonald et al. (2000).
Table 2.5 Heavy metal content in various species of the Kanwar wetland.
Species | Cr (mg/kg) | Mn (mg/kg) | Cu (mg/kg) | Zn (mg/kg) | Pb (mg/kg) | Cd (mg/kg) |
---|---|---|---|---|---|---|
Hydrilla | 111–164 | 116–148 | 38.5–55 | 9.6–12.85 | 133–158 | 0.89–0.98 |
Eichhornia | 172–224 | 72–88 | 48–72 | 8.0–18 | 212–252 | 1.8–2.8 |
Lotus | 28–46 | 26–42 | 12–31 | 6.0–22 | 114–163 | 1.02–1.8 |
Fish | 22–36 | 12.0–26 | 5.3–21.5 | 6.24–20 | 146–172 | 0.97–1 |
Sorghum | 58–92 | 12.6–23 | 22.5–52 | 4.0–15 | 217–264 | 1.01–1.26 |
Wheat | 38.3–42 | 24–25.7 | 27.2–39 | 8.52–9.63 | 95.9–101 | 0.98–1.25 |
Maize | 32–34.41 | 16.5–19 | 15.2–16.9 | 7.15–8.27 | 89–111 | 0.97–1.1 |
Rice | 42–46.63 | 8.14–8.93 | 23–25.44 | 5.5–6.2 | 101–105 | 0.9–1.15 |
Permissible limit | 1a | 1b | 30b | 50b | 5c | 0.3c |
Indian Standardd | 20 | NA | 30 | 50 | 2.5 | 1.5 |
NA: not available.
a GB2762 (2012).
b CODEX (2001).
c FAO/WHO (2011).
d Awashthi (2000).
Figure 2.10 Health risk index of heavy metals via cultivated crop grains in the Kanwar wetland.