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In general, the electrolytes for the SC application need to follow some requirements: (1) broad potential window; (2) high ionic conductivity; (3) broad operating temperature range; (4) non-volatile and non-flammable nature; (5) better chemical and electrochemical stability; (6) chemically inert toward SC cell components such as electrodes, current collectors; and (7) cost-effective and environmentally friendly. The prepared polymer electrolyte needs to be examined on the basis of the characteristic parameter that influences the morphological, structural and electrical properties [14–16]. These important parameters are influenced by the host polymer, salt and nanofiller addition. This section discusses the important parameters.